The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogen oxides / Br oxides / BrOOBr / Harwood(1998)_222-250K_296.9-388.9nm

DATAFILE: BrOOBr_Harwood(1998)_222-250K_296.9-388.9nm.txt
NAME: dibromine dioxide, bromine monoxide dimer, bromine peroxide
FORMULA: BrOOBr
AUTHOR(YEAR): Harwood(1998)
T: 222-250K
λ: 296.9-388.9nm
BIBLIOGRAPHY: M.H. Harwood, D.M. Rowley, R.A. Cox, and R.L. Jones, "Kinetics and mechanism of the BrO self-reaction: Temperature- and pressure-dependent studies", J. Phys. Chem. A 102, 1790-1802 (1998); DOI: 10.1021/jp973264p
COMMENTS: Flash photolysis/UV absorption technique has been used to study the self-reaction of BrO radicals at 222-298 K

The spectrum attributed to BrOOBr and shown in Fig. 9 has been digitzed

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